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Newly arrived on DVD is the ITV mini-series, “ Broadchurch,” which aired here on BBC America. As straightforward as a good British mystery, “Broadchurch” takes full advantage of its nearly 400-minute length to solve a heinous crime that has impacted a scenic and normally placid tourist community on the English Channel. One morning in the off-season, the body of an 11-year-old boy is discovered on the beach, only a few feet distant from a nearly vertical cliff. There’s no reason to believe that Danny Latimer jumped or was pushed to his death. Neither was he sexually abused or washed up on the sand by waves. As these sorts of whodunits and procedurals go, it’s a dandy mystery. What distinguishes “Broadchurch” from other multi-part mysteries we’ve all seen are the many parallel dramas that unfold as the investigation continues. Chief among them is the steadily evolving professional relationship between the intense, by-the-book Detective Inspector Alec Hardy (David Tennant) and the compassionate Detective Sergeant Ellie Miller (Olivia Colman), who is disappointed that she didn’t get the DI position that went to Hardy. The other key relationship is the steadily disintegrating one between the victim’s parents, Beth and Mark Latimer. In time, more than a dozen other townsfolk are interrogated as “persons of interest. They range from Danny’s friends and neighbors, to the local vicar and a spooky psychic. Once those characters are introduced, their lives, too, are peeled back like onion skin to reveal buried secrets. The temperament of a town in distress can be calculated in the roiling sea and the pale sky.

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Scientists now have an understanding of how the catalytic activity, mechanism, and reaction pathways depend on three factors. These factors are the concentration and strength of acid sites, the steric constraints for the reaction, and the identity of the alkylating agent. Detailed kinetic and spectroscopy analyses showed that phenol alkylation with cyclohexanol does not appreciably occur before a majority of cyclohexanol has been dehydrated to cyclohexene. Alkylation reactions are slowed as long as the alcohol is present. In contrast, alkylation products are readily formed when the solution initially contains just phenol and cyclohexene. A combination of in situ MAS-NMR spectroscopy and the use of carbon-13 isotope enriched phenol and cyclohexanol allowed the identification of the reaction pathway that is difficult to probe by other spectroscopy methods. The reaction sequence does not occur as a result of competitive adsorption but by the absence of a reactive electrophile. This is due to the preferential formation of adsorption complexes, i. . protonated alcohol dimers at Bronsted acid sites, which hinder the adsorption of cyclohexene. At low coverage of the acid sites by protonated dimers, cyclohexene adsorption and protonation yields cyclohexyl carbenium ions, which attack phenol to produce alkylated products. This further implies that protonated cyclohexanol dimers dehydrate without the formation of carbenium ions. Explore further: Taking a cue from nature: Turning alcohols into alkylating agents More information: Zhenchao Zhao et al.


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Ninja exploitation flick from 1988, Featuring Richard Harrison. From Joseph Lai’s infamous IFD Films ? urkish edition ex-rental betamax video tape. Italian giallo from 1977, directed by Antonio Bido. Directed by Guido Zurli 1 sheet 67x100 cm; UNFOLDED. Directed by Italo Martinenghi 1 sheet 68x100 cm; UNFOLDED. This is the first version of the two, second one is coming soon. Omer the Tourist in Star Trek, a. . . the Turkish Star Trek. They remade famous movies with no regard for copyright. It plays out like the original Trek's The Man Trap but Turkish character Turist Omer is beamed aboard for hijinks.