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4 These excellent mechanical properties of the nanocomposites resulted from the uniformly dispersed layered silicate in the elastomer matrix, and the strong interaction between the nanoclay layers and rubber chains. These mechanical property improvements are thought to be due to the restriction of polymer chain rearrangement by the dispersion and interaction of the montmorillonite layers. Comparing the mechanical properties of nanocomposites with the conventional filled compounds at the same filler content (approximately 5wt. ) showed that the nanocomposites had much higher modulus and much lower elongation at break. Indeed, the tensile modulus was similar to that of the conventional compounds filled with 30wt. carbon black. 0 12. Comparison of properties achieved in rubber-clay nanocomposites The previous section has looked largely at the nanocomposites from the point of view of the different materials, the methods of processing and degree of dispersion. This behavior was a result of the existence of amine groups in the nanosilicate structure which come from the organo- philization of the layered silicate, as well as the intercalation of octadecylamine between clay galleries which further facilitate the vulcanization reaction. 6 The torque value of NR nanocomposites increased remarkably with the presence of organoclay, as compared with the unfilled NR. It has been found that the tensile properties of these rubbers were influenced by one or more of the following factors: clay loading level, type of curing system, mixing conditions, rubber grade, nanocomposite preparation method, and type of alkyl-ammonium (clay modifier) used. The improvement in the thermal stability is probably due to the high surface area of such nanocomposites, which prevents the volatile decomposition products from diffusing out during the high temperature degradation process. 6,49,57,59 12.

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The first four golden tickets are found by the gluttonous Augustus Gloop, the spoiled and petulant Veruca Salt, the gum-addicted Violet Beauregarde, and the TV-obsessed Mike Teavee. One day, Charlie sees a fifty-pence coin (dollar bill in the US version) buried in the snow. He then buys himself a Wonka Bar and finds the fifth golden ticket and shows it to his parents. The ticket says he can bring any family members with him to the factory and Charlie's parents decide to allow Grandpa Joe to go with him. After meeting Mr. Wonka, the kids and their parents go inside where they meet Oompa-Loompas, a race of small people who help Mr. Wonka operate the factory since he rescued them from poverty and fear in their home country Loompaland. The other kids are ejected from the factory in comical, mysterious and painful ways. They ride the Great Glass Elevator to Charlie's house while the other four children go home after their demises (Augustus squeezed thin, Violet all blue in the face, Veruca covered in garbage, and Mike stretched ten feet tall). Or the more I know the Highlander, the more I want to cuddle him because of hi. Or the more I know the Highlander, the more I want to cuddle him because of his sad background. The plot was great. Just imagine it, writing to a phantom only for him to exist, no conjuring involved.

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Sam G Lady Lauren The Tyrell Navy is with Danny but the Tyrell lands are HUGE and with little protection from the also HUGE Lannister Army Robert Laurens Norgaard I think he was referring to the Lannister forces riding south and taking Tyrell land. Stannis the grammar Nazi what happened to ser pounce Lady Lauren I'm so excited and terrified. Leaked pictures from the set of the new season of GoT. He was the father of Edmure, Catelyn and Lysa and the older brother of Brynden. He ruled over the Riverlands from the castle of Riverrun. During the War of the Five Kings, he declared for House Stark and his grandson Robb Stark, the King in the North. The Riverlands are one of the constituent regions of the Seven Kingdoms and House Tully is one of the Great Houses of the realm. They have three children, two daughters Catelyn and Lysa and a son, Edmure. Minisa died shortly after bearing their last child, which died with her. Hoster joined House Stark, House Baratheon and House Arryn in opposing the Mad King. Catelyn married Brandon's brother Eddard Stark and Hoster arranged for Lysa to marry Lord Jon Arryn to solidify the alliance. They won the war and installed Robert Baratheon as the King on the Iron Throne. His son and heir Edmure took over the day-to-day rule of Riverrun, and Hoster's other duties as overlord of the Riverlands.

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Lots of sexual content revolves around Ben (Dylan McDermott). Also, I don't want to spoil anything, so all I can say is that some of the sex (not all) is crucial to the story. Probably around 13 is a reasonable age to watch this show, but until they're around 14, i recommend watching it with them just to censor anything out. I can only suspect that there will be more sex and violence in future episodes. Because each season has a separate story, I'll dissect each one separately: Season one should be fine for teens, and never disturbed me in any way. Season 2 is the scary season, and the villain has a very disturbing fetish. I would say save this season for teens, unless they have thick skin. Season 3 has one brief scene where a girl is roofied and almost raped. However, season 3 focuses on girl power, and this is a teaching moment. In the first episode, a man masturbates after walking in on a woman masturbating this was after the wife caught him in bed with one of his students and cuts his arm with a knife and then the daughter is shown smoking and the wife is haunted by two dead kids. The smoking gets the girl in a cat fight which leads to them torturing the girl who started it. The girl is shown cutting right as one of her dad's mental patients walks in and tells her how to kill herself instead of cutting across her wrists. But You don't see much in the sex scenes, you hear it and then only see them naked from their backside.

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We didn’t lose the technology, as some have claimed, we just stopped making it, at least for those specific uses. Yes, the reasons behind the race to the Moon in the 60s were very political, that’s surely no secret. But in just eight years we went from sending the first American on a brief suborbital flight to safely landing astronauts on the surface of another world and bringing them home again, an incredible feat accomplished only through the talent and hard work of literally hundreds of thousands of people—over 400,000, in fact ( source )—and the support and financial backing of an entire nation. For most of them, I just feel sorry that we failed in their education. . Therefore, our understanding is that it’s an error on editing stage of production: the production company took wrong clips and audio and used in the documentary. “ This erroneous claim has been debunked many times but is still often brought up by Moon landing deniers who are more than happy to cite misedited footage as credible evidence. ( Source ). If the Moon landings were faked somehow, based on his numbers it’d have become widely-known by 1973. He very clearly has a suit and helmet on, and isn’t some “long-haired stagehand” as erroneously accused. I could see more stars than I could possibly imagine. . I’m just sorry that you have so little faith in what humans can achieve.

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The Seahawks defense reinforced by the return of safety Earl Thomas bottled up receivers from making many big plays and put plenty of pressure on Rodgers. ut the Packers started denting Seattle with runs or quick passes to Nelson, Randall Cobb and Montgomery in the second half, chewing up clock in the process. Another victim was found in a field nearby, bringing the total number of people found to 39. Early in the 20th century, food horror stories like Upton Sinclair’s “The Jungle” start to frighten the American public. Quarterback Cam Newton did not play in the preseason while rehabbing from a shoulder surgery, but he’s expected to start Sunday. Each side is designated to a specific team and their helmet design. These mascots are often as beloved by fans as the team itself. “They’re just too undependable for me,” Belichick told reporters. And of course, they’re also the hardest tickets to snag. He might turn out to be a 13 year NFL starter, but Trubisky is a risk, having started just 13 collegiate games. engals: A team that needed defensive help went all offense early in the draft, and it went with risks. If the Chargers rebound from a 5 11 season and challenge for a playoff spot, and if their offense is high powered and entertaining, their temporary home for three seasons could, at times, sound something like an NFL stadium. Even when the Raiders struggled defensively a year ago, they did thrive at taking the ball away.

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The kind of movie that came out exactly at the wrong time. She flew off into the clouds over a half century ago, and now she’s returned with a new look, some new music, and several impossible leaps forward in animation technology. Julie Andrews was too young, too bubbly, and too likable for her taste. Of course she was perfect (not just practically) for everyone else. Andrews owned the role, making it almost unthinkable that someone else could take up the mantel. She has to simultaneously make us remember Andrews and be comfortable without her. To evoke the spirit of the character as so many remember her without stepping on her toes or clinging too closely. His image has been frozen in amber twice during his career, offering us only the cigar-chomping, heavily tanned silence of Sergio Leone’s “Dollars Trilogy” and the gray-headed, lawn protector of Gran Torino. One is a genre king during the halcyon days of wild west romanticism; the other is the fantasy fulfillment of old man anger at the world. One is everyone’s dad’s favorite actor; the other is what almost everyone’s dad has morphed into over the past twenty years. He made not one, but two buddy comedies with an orangutan after all. Yet even though he talked enough as Dirty Harry to earn a globally-recognized (and almost always misquoted) catch phrase, his unhinged detective was a simmering extension of his tight-lipped western anti-heroes. For the two young women at the center of Vox Lux, it’s both.